The
major quality requirements of coal for Sopnge iron production are
1) Non-cooking
characteristics
2) Low ash content
3) Low sulphur content
4) Good reactivity
5) High ash fusion
temperature
6) Medium volatile
matter
a)
Non-cooking character Non-cooking coal is required in sponge
iron production, since the cooking reaction leads
to formation of rings inside the kiln. Practically permissible
caking index is 3 maximum for rotory kiln operations.
b)
Low ash content High ash leads to under utilization of
the kiln volume available for reduction it
also increases the consumption of fixed carbon since
additional energy is consumed in heating the inert
ash mass to reaction temperature. An ash content 30 percent
maximum is the practicable limit for normal operation.
c)
Low sulphur content To control the sulphur in sponge iron the sulphur in coal
should be one percent maximum.
d)
Good reactivity An important step in solid state reduction
is the boundward reaction, whereby carbondioxide generated
from burning of coal reacts with coal to regenerate
carbon monoxide generated from the coal,
therefore, should be possess sufficient "reactivity" so
that the bounded reaction proceeds Bituminous and
sub-bituminous coal exhibits very good suitable
for production of sponge iron.
e)
High ash fusion temperature Coals with low ash fusion temperature leads to sticky and
consequent unstable kiln operation by forming accretion
inside the kiln, and reducing the reduction
rate by forming of slag layer on surface
of the ore. Hence coals with ash fusion temperature above 1150°C
are desirable for rotory kiln operation. Ash temperature is
governed by its chemistry. Coal with ash of high sulphuric
trioxide equivalent low silica ratio and high alkali ratio
has lower eutectic temperature and hence is not desirable.
f)
Medium volatile matter
Coals with optimum volatile content are required for coal based rotory
kiln process. Coal with very low volatile matter result in very low
reactivity of char and thus give rise to poorly metallised product.
Very high volatile coals, though they yield highly reactive char,
are also not preferred. Generally for rotory kiln process volatile
matter should be in the range of 28 to 32 percent.